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泥水盾构 9

砂卵石地层 3

铝电解 3

低温铝电解 2

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同步注浆 2

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盾构 2

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Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1405-7

摘要：

• Copper fractal growth was observed during WPCBs recycling by slurry electrolysis.

关键词： Dendritic copper     Fractal growth     WPCBs     Slurry electrolysis    

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矿浆电解过程的浸出机理

杨显万,张英杰,邓纶浩,邱定蕃

《中国工程科学》 2000年 第2卷 第6期   页码 49-51

摘要：

介绍了高铅铜型难处理金矿矿浆电解浸出机理的研究结果。金精矿在矿浆电解时，铅的浸出可通过化学溶解、化学氧化、阳极氧化三种途径；铅浸出的主要途径是靠化学溶解，矿粒与阳极接触而被氧化对浸出的贡献不大。

关键词： 矿浆电解     浸出     机理    

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清洁高效的提取冶金——矿浆电解

邱定蕃

《中国工程科学》 1999年 第1卷 第1期   页码 67-72

摘要：

环境污染和能源短缺是重有色金属冶炼的两大障碍。在对重有色金属湿法冶金存在主要问题进行分析的基础上研究成功的矿浆电解新技术，是一种清洁、高效的提取冶金。它具有流程短、能耗低、金属分离好和环境污染少等特点。矿浆电解的显著特点是充分利用了电积过程的阳极反应来浸出矿石，工艺能耗大大降低；在电解槽中硫化物转化为元素硫，而不产生硫酸，有利于环境保护。文章描述了国内外矿浆电解技术的发展过程及我国建立的世界上第一个矿浆电解工业生产厂的概况，指出我国在该领域处于世界领先地位和矿浆电解技术具有很好的前景。

关键词： 重有色金属     湿法冶金     矿浆电解     提取冶金    

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Experimental study on slurry-induced fracturing during shield tunneling

Teng WANG, Dajun YUAN, Dalong JIN, Xinggao LI

《结构与土木工程前沿（英文）》 2021年 第15卷 第2期   页码 333-345 doi: 10.1007/s11709-021-0718-8

摘要： Facial support in slurry shield tunneling is provided by slurry pressure to balance the external earth and water pressure. Hydraulic fracturing may occur and cause a significant decrease in the support pressure if the slurry pressure exceeds the threshold of the soil or rock material, resulting in a serious face collapse accident. Preventing the occurrence of hydraulic fracturing in a slurry shield requires investigating the effects of related influencing factors on the hydraulic fracturing pressure and fracture pattern. In this study, a hydraulic fracturing apparatus was developed to test the slurry-induced fracturing of cohesive soil. The effects of different sample parameters and loading conditions, including types of holes, unconfined compressive strength, slurry viscosity, and axial and circumferential loads, on the fracturing pressure and fracture dip were examined. The results indicate that the fracture dip is mainly affected by the deviator stress. The fracturing pressure increases linearly with the increase in the circumferential pressure, but it is almost independent of the axial pressure. The unconfined compressive strength of soil can reflect its ability to resist fracturing failure. The fracturing pressure increases with an increase in the unconfined compressive strength as well as the slurry viscosity. Based on the test results, an empirical approach was proposed to estimate the fracturing pressure of the soil.

关键词： slurry shield tunneling     hydraulic fracturing test     fracturing pressure     fracture dip     unconfined compressive strength     slurry viscosity    

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Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 139-144 doi: 10.1007/s11705-013-1323-8

摘要： Coker gas oil (CGO) is a poor-quality feedstock for fluidized bed catalytic cracking (FCC) or hydrocracking. The pretreatment of CGO, especially hydrotreating, can significantly improve the product quality and protect the catalyst. In this work, we studied the hydrodesulfurization (HDS) of CGO in a slurry reactor. All the experiments were carried out in an autoclave using a NiMo/Al O catalyst at reaction temperature 340°C–400°C, pressure 6–10 MPa, and stirring speed 800 r·min , with hydrogen-to-oil ratio in the range of 500–1500. The effects of the operating parameters on the desulfurization ratio were investigated and discussed. A macro reaction kinetic model was established for the HDS of CGO in the slurry reactor.

关键词： coker gas oil     hydrodesulfurization     slurry reactor     reaction kinetic model    

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Experimental study on the stratum applicability and mechanisms of bubble–slurry for earth pressure balance

《结构与土木工程前沿（英文）》   页码 1387-1399 doi: 10.1007/s11709-023-0005-y

摘要： Soil conditioning is essential for addressing the stratum applicability problem of earth pressure balance (EPB) shields. Under high water pressures, EPB shields spew water and soil when excavating coarse-grained strata. Typically, foam combined with polymers and slurry is used to solve spewing. However, in current techniques, slurry, foam, and the other agents are mixed with soil separately, their synergistic effect is seldom realized. In this study, an anionic surfactant was used to foam in bentonite slurry to form bubble–slurry to maximize the synergy between bubbles and slurry. The slump, volume stability, and permeability test of bubble–slurry-conditioned sand was conducted to examine the conditioning effect, and the stratum applicability of bubble–slurry was determined from the perspective of permeability. It was found that the conditioning effect of bubble–slurry in coarse gravel soil was excellent and could expand the applicability of EPB shields. The main stabilization mechanism of bubble–slurry is that bentonite particles provide a space barrier for bubbles. And three seepage modes of bubble–slurry-conditioned sand were innovatively defined, and the occurrence conditions of the three seepage modes were analyzed according to the permeability coefficient of sand, initial dynamic shear force of bubble–slurry, and hydraulic gradient.

关键词： EPB shield     bubble–slurry     soil conditioning     stability     permeability    

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Study on direct alcohol/ether fuel synthesis process in bubble column slurry reactor

Zhen CHEN, Haitao ZHANG, Weiyong YING, Dingye FANG

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 461-471 doi: 10.1007/s11705-010-0517-6

摘要： The recent studies of direct alcohol/ether synthesis process in slurry reactors were reviewed, and the research work in our laboratory was carried out in this paper. a global kinetics model for direct dimethyl ether (DME) synthesis from syngas over a novel Cu-Zn-Al-Zr slurry catalyst was established according to the total of 25 experimental data, and a steady-state one-dimensional mathematical model was further developed in bubble column slurry reactor (BCSR), which was assumed that the bubble phase was plug flow, and the liquid phase was fully mixed flow. The numerical simulations of reactor design of 100000 t/a dimethyl ether pilot plant indicate that higher pressure and lower temperature were favorable to the increase of CO conversion, selectivity of dimethyl ether, product yield and height of slurry bed. The optimal operating conditions for DME synthesis process were obtained: reaction temperature at 240°C, reactor pressure at 5 MPa and reactor diameter of 2.5 m.

关键词： syngas     alcohol/ether fuel     slurry catalyst     bubble column slurry reactor     global kinetics     mathematical model    

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Numerical simulation on flow of ice slurry in horizontal straight tube

Shengchun LIU,Ming SONG,Ling HAO,Pengxiao WANG

《能源前沿（英文）》 2021年 第15卷 第1期   页码 201-207 doi: 10.1007/s11708-017-0451-0

摘要： Numerical simulation on flow of ice slurry in horizontal straight tubes was conducted in this paper to improve its transportation characteristics and application. This paper determined the influence of the diameter and length of tubes, the ice packing factors (IPF) and the flow velocity of ice slurry on pressure loss by using numerical simulation, based on two-phase flow and the granular dynamic theory. Furthermore, it was found that the deviation between the simulation results and experimental data could be reduced from 20% to 5% by adjusting the viscosity which was reflected by velocity. This confirmed the reliability of the simulation model. Thus, two mathematical correlations between viscosity and flow velocity were developed eventually. It could also be concluded that future rheological model of ice slurry should be considered in three sections clarified by the flow velocity, which determined the fundamental difference from single-phase fluid.

关键词： ice slurry     horizontal tubes     numerical simulation     pressure drop     viscosity model    

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The world’s first offshore wind power non-desalination of seawater electrolysis for hydrogen production

《能源前沿（英文）》 2023年 第17卷 第3期   页码 317-319 doi: 10.1007/s11708-023-0888-2

摘要： The world’s first offshore wind power non-desalination of seawater electrolysis for hydrogen production successfully tested in Fujian, China

关键词： China     wind power non    

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Development and demonstration plant operation of an opposed multi-burner coal-water slurry gasification

WANG Fuchen, ZHOU Zhijie, DAI Zhenhua, GONG Xin, YU Guangsuo, LIU Haifeng, WANG Yifei, YU Zunhong

《能源前沿（英文）》 2007年 第1卷 第3期   页码 251-258 doi: 10.1007/s11708-007-0035-5

摘要： The features of the opposed multi-burner (OMB) gasification technology, the method and process of the research, and the operation results of a pilot plant and demonstration plants have been introduced. The operation results of the demonstration plants show that when Beisu coal was used as feedstock, the OMB CWS gasification process at Yankuang Cathy Coal Co. Ltd had a higher carbon conversion of 3%, a lower specific oxygen consumption of about 8%, and a lower specific carbon consumption of 2%–3% than that of Texaco CWS gasification at the Lunan Fertilizer Plant. When Shenfu coal was used as feedstock, the OMB CWS gasification process at Hua-lu Heng-sheng Chemical Co. Ltd had a higher carbon conversion of more than 3%, a lower specific oxygen consumption of about 2%, and a lower specific coal consumption of about 8% than that of the Texaco CWS gasification process at Shanghai Coking & Chemical Corporation. The OMB CWS gasification technology is proven by industrial experience to have a high product yield, low oxygen and coal consumption and robust and safe operation.
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Application of gamma-ray attenuation technology in density measurement of a slurry reactor

Jian XU, Weisheng WEI, Kai ZHANG

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 486-490 doi: 10.1007/s11705-010-0509-6

摘要： Axial density profile of the gas-liquid-solid mixture in a slurry bubble column was measured by gamma-ray attenuation technology. Several measures for improving measurement precision were presented based on the discussion on attenuation law. It was found that the response frequency and the ray intensity should be as high as possible to improve the measurement precision. The mass absorption coefficient depended on not the object’s thickness but the location where the object was placed between the ray source and the detector. The results showed that the density in the column decreases with the increase of column height, which indicates that the measurement by gamma-ray attenuation is reasonable.

关键词： slurry reactor     axial density distribution     gamma-ray attenuation technology    

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砂卵石条件下泥水分离技术研究与应用

王广余,孙善辉,苏清贵

《中国工程科学》 2010年 第12卷 第12期   页码 41-45

摘要：

通过北京铁路北京站至北京西站地下直径线工程泥水处理系统的研究与应用实践经验，总结了城市繁华地段砂卵石条件下大直径盾构泥水分离应用技术，希望对类似工程有借鉴作用。

关键词： 泥水盾构     泥水分离     压滤    

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Advances in the slurry reactor technology of the anthraquinone process for H

Hongbo Li, Bo Zheng, Zhiyong Pan, Baoning Zong, Minghua Qiao

《化学科学与工程前沿（英文）》 2018年 第12卷 第1期   页码 124-131 doi: 10.1007/s11705-017-1676-5

摘要： This paper overviews the development of the anthraquinone auto-oxidation (AO) process for the production of hydrogen peroxide in China and abroad. The characteristics and differences between the fixed-bed and fluidized-bed reactors for the AO process are presented. The detailed comparison indicates that the production of hydrogen peroxide with the fluidized-bed reactor has many advantages, such as lower operation cost and catalyst consumption, less anthraquinone degradation, higher catalyst utilization efficiency, and higher hydrogenation efficiency. The key characters of the production technology of hydrogen peroxide based on the fluidized-bed reactor developed by the Research Institute of Petroleum Processing, Sinopec are also disclosed. It is apparent that substituting the fluidized-bed reactor for the fixed-bed reactor is a major direction of breakthrough for the production technology of hydrogen peroxide in China.

关键词： anthraquinone process     fixed-bed reactor     slurry-bed reactor     hydrogen peroxide    

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Microbial electrolysis cells with biocathodes and driven by microbial fuel cells for simultaneous enhanced

Jingya SHEN,Yuliang SUN,Liping HUANG,Jinhui YANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第6期   页码 1084-1095 doi: 10.1007/s11783-015-0805-y

摘要： Cobalt and copper recovery from aqueous Co(II) and Cu(II) is one critical step for cobalt and copper wastewaters treatment. Previous tests have primarily examined Cu(II) and Co(II) removal in microbial electrolysis cells (MECs) with abiotic cathodes and driven by microbial fuel cell (MFCs). However, Cu(II) and Co(II) removal rates were still slow. Here we report MECs with biocathodes and driven by MFCs where enhanced removal rates of 6.0±0.2 mg?L ?h for Cu(II) at an initial concentration of 50 mg?L and 5.3±0.4 mg?L h for Co(II) at an initial 40 mg?L were achieved, 1.7 times and 3.3 times as high as those in MECs with abiotic cathodes and driven by MFCs. Species of Cu(II) was reduced to pure copper on the cathodes of MFCs whereas Co(II) was removed associated with microorganisms on the cathodes of the connected MECs. Higher Cu(II) concentrations and smaller working volumes in the cathode chambers of MFCs further improved removal rates of Cu(II) (115.7 mg?L ?h ) and Co(II) (6.4 mg?L ?h ) with concomitantly achieving hydrogen generation (0.05±0.00 mol?mol COD). Phylogenetic analysis on the biocathodes indicates dominantly accounted for 67.9% of the total reads, followed by (14.0%), (6.1%), (2.5%), (1.4%), and (1.0%). This study provides a beneficial attempt to achieve simultaneous enhanced Cu(II) and Co(II) removal, and efficient Cu(II) and Co(II) wastewaters treatment without any external energy consumption.

关键词： biocathode     microbial electrolysis cell     microbial fuel cell     Cu(II) removal     Co(II) removal    

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Aggregating structure in coal water slurry studied by eDLVO theory and fractal dimension

Qiang LI, Qian WANG, Jian HOU, Jiansheng ZHANG, Yang ZHANG

《能源前沿（英文）》 2023年 第17卷 第2期   页码 306-316 doi: 10.1007/s11708-021-0736-1

摘要： Coal water slurry gasification is a main source of hydrogen in the developing hydrogen economy. Moreover, biomass and waste can be added, making gasification process greener. To expand the application of coal water slurry and gasification process, it is necessary to understand the micro-structure in this large particle suspension system. In this paper, the micro-structure in coal water slurry was studied by extended DLVO (eDLVO) theory and fractal dimension, which is used to explain the mechanism of stability in large particle suspension systems. The interaction between two coal particles was characterized from the interparticle potential and energy barrier based on the eDLVO theory. The rheology and stability between different types of coals are measured and explained by the aggregating structure and fractal dimension in coal water slurry. The results indicated that there would be an aggregating structure in high rank coals, due to the interparticle potential caused by the surface properties, but probably not in low rank coals. This aggregating structure can be described and characterized by fractal dimension. The aggregation of particles is the source of the stability for high rank coals, as the close-packed 3D network structure in large particle suspension can support coal particles from settling down. The results have demonstrated that the combination of the eDLVO theory and rheological measurement is an effective way to investigate the stability of large particle suspension systems.

关键词： coal water slurry     extended DLVO (eDLVO)     fractal dimension     stability    

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标题 作者 时间 类型 操作

Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

期刊论文

矿浆电解过程的浸出机理

杨显万,张英杰,邓纶浩,邱定蕃

期刊论文

清洁高效的提取冶金——矿浆电解

邱定蕃

期刊论文

Experimental study on slurry-induced fracturing during shield tunneling

Teng WANG, Dajun YUAN, Dalong JIN, Xinggao LI

期刊论文

Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

期刊论文

Experimental study on the stratum applicability and mechanisms of bubble–slurry for earth pressure balance

期刊论文

Study on direct alcohol/ether fuel synthesis process in bubble column slurry reactor

Zhen CHEN, Haitao ZHANG, Weiyong YING, Dingye FANG

期刊论文

Numerical simulation on flow of ice slurry in horizontal straight tube

Shengchun LIU,Ming SONG,Ling HAO,Pengxiao WANG

期刊论文

The world’s first offshore wind power non-desalination of seawater electrolysis for hydrogen production

期刊论文

Development and demonstration plant operation of an opposed multi-burner coal-water slurry gasification

WANG Fuchen, ZHOU Zhijie, DAI Zhenhua, GONG Xin, YU Guangsuo, LIU Haifeng, WANG Yifei, YU Zunhong

期刊论文

Application of gamma-ray attenuation technology in density measurement of a slurry reactor

Jian XU, Weisheng WEI, Kai ZHANG

期刊论文

砂卵石条件下泥水分离技术研究与应用

王广余,孙善辉,苏清贵

期刊论文

Advances in the slurry reactor technology of the anthraquinone process for H

Hongbo Li, Bo Zheng, Zhiyong Pan, Baoning Zong, Minghua Qiao

期刊论文

Microbial electrolysis cells with biocathodes and driven by microbial fuel cells for simultaneous enhanced

Jingya SHEN,Yuliang SUN,Liping HUANG,Jinhui YANG

期刊论文

Aggregating structure in coal water slurry studied by eDLVO theory and fractal dimension

Qiang LI, Qian WANG, Jian HOU, Jiansheng ZHANG, Yang ZHANG

期刊论文